Can extension methods be applied to interfaces?

Of course they can; most of Linq is built around interface extension methods.

Interfaces were actually one of the driving forces for the development of extension methods; since they can't implement any of their own functionality, extension methods are the easiest way of associating actual code with interface definitions.

See the Enumerable class for a whole collection of extension methods built around IEnumerable<T>. To implement one, it's the same as implementing one for a class:

public static class TopologyExtensions
{
    public static void CountNodes(this ITopology topology)
    {
        // ...
    }
}

There's nothing particularly different about extension methods as far as interfaces are concerned; an extension method is just a static method that the compiler applies some syntactic sugar to to make it look like the method is part of the target type.